Superlattice

A superlattice is a periodic structure of layers of two (or more) materials. Typically, the thickness of one layer is several nanometers. It can also refer to a lower-dimensional structure such as an array of quantum dots or quantum wires.

Superlattices were discovered early in 1925 by Johansson and Linde[1] after the studies on gold-copper and palladium-copper systems through their special X-ray diffraction patterns. Further experimental observations and theoretical modifications on the field were done by Bradley and Jay,[2] Gorsky,[3] Borelius,[4] Dehlinger and Graf,[5] Bragg and Williams[6] and Bethe.[7] Theories were based on the transition of arrangement of atoms in crystal lattices from disordered state to an ordered state.

J.S. Koehler theoretically predicted[8] that by using alternate (nano-)layers of materials with high and low elastic constants, shearing resistance is improved by up to 100 times as the Frank–Read source of dislocations cannot operate in the nanolayers.

The increased mechanical hardness of such superlattice materials was confirmed firstly by Lehoczky in 1978 on Al-Cu and Al-Ag,[9] and later on by several others, e.g. Barnett and Sproul[10] on hard PVD coatings.

If the superlattice is made of two semiconductor materials with different band gaps, each quantum well sets up new selection rules that affect the conditions for charges to flow through the structure. The two different semiconductor materials are deposited alternately on each other to form a periodic structure in the growth direction. Since the 1970 proposal of synthetic superlattices by Esaki and Tsu,[11] advances in the physics of such ultra-fine semiconductors, presently called quantum structures, have been made. The concept of quantum confinement has led to the observation of quantum size effects in isolated quantum well heterostructures and is closely related to superlattices through the tunneling phenomena. Therefore, these two ideas are often discussed on the same physical basis, but each has different physics useful for applications in electric and optical devices.

Superlattice miniband structures depend on the heterostructure type, either type I, type II or type III. For type I the bottom of the conduction band and the top of the valence subband are formed in the same semiconductor layer. In type II the conduction and valence subbands are staggered in both real and reciprocal space, so that electrons and holes are confined in different layers. Type III superlattices involve semimetal material, such as HgTe/CdTe. Although the bottom of the conduction subband and the top of the valence subband are formed in the same semiconductor layer in Type III superlattice, which is similar with Type I superlattice, the band gap of Type III superlattices can be continuously adjusted from semiconductor to zero band gap material and to semimetal with negative band gap.

Another class of quasiperiodic superlattices is named after Fibonacci. A Fibonacci superlattice can be viewed as a one-dimensional quasicrystal, where either electron hopping transfer or on-site energy takes two values arranged in a Fibonacci sequence.

GaAs/AlAs superlattice and potential profile of conduction and valence bands along the growth direction (z).

Semiconductor materials, which are used to fabricate the superlattice structures, may be divided by the element groups, IV, III-V and II-VI. While group III-V semiconductors (especially GaAs/AlxGa1−xAs) have been extensively studied, group IV heterostructures such as the SixGe1−x system are much more difficult to realize because of the large lattice mismatch. Nevertheless, the strain modification of the subband structures is interesting in these quantum structures and has attracted much attention.

In the GaAs/AlAs system both the difference in lattice constant between GaAs and AlAs and the difference of their thermal expansion coefficient are small. Thus, the remaining strain at room temperature can be minimized after cooling from epitaxial growth temperatures. The first compositional superlattice was realized using the GaAs/AlxGa1−xAs material system.

A graphene/boron nitride system forms a semiconductor superlattice once the two crystals are aligned. Its charge carriers move perpendicular to the electric field, with little energy dissipation. h-BN has a hexagonal structure similar to graphene's. The superlattice has broken inversion symmetry. Locally, topological currents are comparable in strength to the applied current, indicating large valley-Hall angles.[12]

Superlattices can be produced using various techniques, but the most common are molecular-beam epitaxy (MBE) and sputtering. With these methods, layers can be produced with thicknesses of only a few atomic spacings. An example of specifying a superlattice is [Fe
20
V
30
]20. It describes a bi-layer of 20Å of Iron (Fe) and 30Å of Vanadium (V) repeated 20 times, thus yielding a total thickness of 1000Å or 100 nm. The MBE technology as a means of fabricating semiconductor superlattices is of primary importance. In addition to the MBE technology, metal-organic chemical vapor deposition (MO-CVD) has contributed to the development of superconductor superlattices, which are composed of quaternary III-V compound semiconductors like InGaAsP alloys. Newer techniques include a combination of gas source handling with ultrahigh vacuum (UHV) technologies such as metal-organic molecules as source materials and gas-source MBE using hybrid gases such as arsine (AsH
3
) and phosphine (PH
3
) have been developed.

Generally speaking MBE is a method of using three temperatures in binary systems, e.g., the substrate temperature, the source material temperature of the group III and the group V elements in the case of III-V compounds.

The structural quality of the produced superlattices can be verified by means of X-ray diffraction or neutron diffraction spectra which contain characteristic satellite peaks. Other effects associated with the alternating layering are: giant magnetoresistance, tunable reflectivity for X-ray and neutron mirrors, neutron spin polarization, and changes in elastic and acoustic properties. Depending on the nature of its components, a superlattice may be called magnetic, optical or semiconducting.

By definition the Bloch functions are delocalized over the whole superlattice. This may provide difficulties if electric fields are applied or effects due to the superlattice's finite length are considered. Therefore, it is often helpful to use different sets of basis states that are better localized. A tempting choice would be the use of eigenstates of single quantum wells. Nevertheless, such a choice has a severe shortcoming: the corresponding states are solutions of two different Hamiltonians, each neglecting the presence of the other well. Thus these states are not orthogonal, creating complications. Typically, the coupling is estimated by the transfer Hamiltonian within this approach. For these reasons, it is more convenient to use the set of Wannier functions.

Overview of the different standard approaches for superlattice transport.

The motion of charge carriers in a superlattice is different from that in the individual layers: mobility of charge carriers can be enhanced, which is beneficial for high-frequency devices, and specific optical properties are used in semiconductor lasers.

If an external bias is applied to a conductor, such as a metal or a semiconductor, typically an electric current is generated. The magnitude of this current is determined by the band structure of the material, scattering processes, the applied field strength and the equilibrium carrier distribution of the conductor.

A particular case of superlattices called superstripes are made of superconducting units separated by spacers. In each miniband the superconducting order parameter, called the superconducting gap, takes different values, producing a multi-gap, or two-gap or multiband superconductivity.

Recently, Felix and Pereira investigated the thermal transport by phonons in periodic[13] and quasiperiodic[14][15][16] superlattices of graphene-hBN according to the Fibonacci sequence. They reported that the contribution of coherent thermal transport (phonons like-wave) was suppressed as quasiperiodicity increased.

Artificial two-dimensional crystals can be viewed as a 2D/2D case (2D modulation of a 2D system) and other combinations are experimentally available: an array of quantum wires (1D/2D) or 3D/3D photonic crystals.

The superlattice of palladium-copper system is used in high performance alloys to enable a higher electrical conductivity, which is favored by the ordered structure. Further alloying elements like silver, rhenium, rhodium and ruthenium are added for better mechanical strength and high temperature stability. This alloy is used for probe needles in probe cards.[19]