# Point group

In geometry, a **point group** is a group of geometric symmetries (isometries) that keep at least one point fixed. Point groups can exist in a Euclidean space with any dimension, and every point group in dimension *d* is a subgroup of the orthogonal group O(*d*). Point groups can be realized as sets of orthogonal matrices *M* that transform point *x* into point *y*:

where the origin is the fixed point. Point-group elements can either be rotations (determinant of *M* = 1) or else reflections, or improper rotations (determinant of *M* = −1).

Discrete point groups in more than one dimension come in infinite families, but from the crystallographic restriction theorem and one of Bieberbach's theorems, each number of dimensions has only a finite number of point groups that are symmetric over some lattice or grid with that number. These are the crystallographic point groups.

Point groups can be classified into *chiral* (or purely rotational) groups and *achiral* groups.^{[1]}
The chiral groups are subgroups of the special orthogonal group SO(*d*): they contain only orientation-preserving orthogonal transformations, i.e., those of determinant +1. The achiral groups contain also transformations of determinant −1. In an achiral group, the orientation-preserving transformations form a (chiral) subgroup of index 2.

Finite Coxeter groups or *reflection groups* are those point groups that are generated purely by a set of reflectional mirrors passing through the same point. A rank *n* Coxeter group has *n* mirrors and is represented by a Coxeter-Dynkin diagram. Coxeter notation offers a bracketed notation equivalent to the Coxeter diagram, with markup symbols for rotational and other subsymmetry point groups. Reflection groups are necessarily achiral (except for the trivial group containing only the identity element).

There are only two one-dimensional point groups, the identity group and the reflection group.

Applying the crystallographic restriction theorem restricts *n* to values 1, 2, 3, 4, and 6 for both families, yielding 10 groups.

The subset of pure reflectional point groups, defined by 1 or 2 mirrors, can also be given by their Coxeter group and related polygons. These include 5 crystallographic groups. The symmetry of the reflectional groups can be doubled by an isomorphism, mapping both mirrors onto each other by a bisecting mirror, doubling the symmetry order.

Point groups in three dimensions, sometimes called **molecular point groups** after their wide use in studying the symmetries of small molecules.

They come in 7 infinite families of axial or prismatic groups, and 7 additional polyhedral or Platonic groups. In Schönflies notation,*

Applying the crystallographic restriction theorem to these groups yields 32 Crystallographic point groups.

The reflection point groups, defined by 1 to 3 mirror planes, can also be given by their Coxeter group and related polyhedra. The [3,3] group can be doubled, written as [[3,3]], mapping the first and last mirrors onto each other, doubling the symmetry to 48, and isomorphic to the [4,3] group.

The four-dimensional point groups (chiral as well as achiral) are listed in Conway and Smith,^{[1]} Section 4, Tables 4.1-4.3.

The following list gives the four-dimensional reflection groups (excluding those that leave a subspace fixed and that are therefore lower-dimensional reflection groups). Each group is specified as a Coxeter group, and like the polyhedral groups of 3D, it can be named by its related convex regular 4-polytope. Related pure rotational groups exist for each with half the order, and can be represented by the bracket Coxeter notation with a '+' exponent, for example [3,3,3]^{+} has three 3-fold gyration points and symmetry order 60. Front-back symmetric groups like [3,3,3] and [3,4,3] can be doubled, shown as double brackets in Coxeter's notation, for example [[3,3,3]] with its order doubled to 240.

The following table gives the five-dimensional reflection groups (excluding those that are lower-dimensional reflection groups), by listing them as Coxeter groups. Related chiral groups exist for each with half the order, and can be represented by the bracket Coxeter notation with a '+' exponent, for example [3,3,3,3]^{+} has four 3-fold gyration points and symmetry order 360.

The following table gives the six-dimensional reflection groups (excluding those that are lower-dimensional reflection groups), by listing them as Coxeter groups. Related pure rotational groups exist for each with half the order, and can be represented by the bracket Coxeter notation with a '+' exponent, for example [3,3,3,3,3]^{+} has five 3-fold gyration points and symmetry order 2520.

The following table gives the seven-dimensional reflection groups (excluding those that are lower-dimensional reflection groups), by listing them as Coxeter groups. Related chiral groups exist for each with half the order, defined by an even number of reflections, and can be represented by the bracket Coxeter notation with a '+' exponent, for example [3,3,3,3,3,3]^{+} has six 3-fold gyration points and symmetry order 20160.

The following table gives the eight-dimensional reflection groups (excluding those that are lower-dimensional reflection groups), by listing them as Coxeter groups. Related chiral groups exist for each with half the order, defined by an even number of reflections, and can be represented by the bracket Coxeter notation with a '+' exponent, for example [3,3,3,3,3,3,3]^{+} has seven 3-fold gyration points and symmetry order 181440.