Matrix mechanics is a formulation of quantum mechanics created by Werner Heisenberg, Max Born, and Pascual Jordan in 1925. It was the first conceptually autonomous and logically consistent formulation of quantum mechanics. Its account of quantum jumps supplanted the Bohr model's electron orbits. It did so by interpreting the physical properties of particles as matrices that evolve in time. It is equivalent to the Schrödinger wave formulation of quantum mechanics, as manifest in Dirac's bra–ket notation.
In some contrast to the wave formulation, it produces spectra of (mostly energy) operators by purely algebraic, ladder operator methods. Relying on these methods, Wolfgang Pauli derived the hydrogen atom spectrum in 1926, before the development of wave mechanics.
In 1925 Werner Heisenberg was working in Göttingen on the problem of calculating the spectral lines of hydrogen. By May 1925 he began trying to describe atomic systems by observables only. On June 7, after weeks of failing to alleviate his hay fever with aspirin and cocaine, Heisenberg left for the pollen-free North Sea island of Helgoland. While there, in between climbing and memorizing poems from Goethe's West-östlicher Diwan, he continued to ponder the spectral issue and eventually realised that adopting non-commuting observables might solve the problem. He later wrote:
It was about three o' clock at night when the final result of the calculation lay before me. At first I was deeply shaken. I was so excited that I could not think of sleep. So I left the house and awaited the sunrise on the top of a rock.
After Heisenberg returned to Göttingen, he showed Wolfgang Pauli his calculations, commenting at one point:
Everything is still vague and unclear to me, but it seems as if the electrons will no more move on orbits.
On July 9 Heisenberg gave the same paper of his calculations to Max Born, saying that "he had written a crazy paper and did not dare to send it in for publication, and that Born should read it and advise him" prior to publication. Heisenberg then departed for a while, leaving Born to analyse the paper.
In the paper, Heisenberg formulated quantum theory without sharp electron orbits. Hendrik Kramers had earlier calculated the relative intensities of spectral lines in the Sommerfeld model by interpreting the Fourier coefficients of the orbits as intensities. But his answer, like all other calculations in the old quantum theory, was only correct for large orbits.
Heisenberg, after a collaboration with Kramers, began to understand that the transition probabilities were not quite classical quantities, because the only frequencies that appear in the Fourier series should be the ones that are observed in quantum jumps, not the fictional ones that come from Fourier-analyzing sharp classical orbits. He replaced the classical Fourier series with a matrix of coefficients, a fuzzed-out quantum analog of the Fourier series. Classically, the Fourier coefficients give the intensity of the emitted radiation, so in quantum mechanics the magnitude of the matrix elements of the position operator were the intensity of radiation in the bright-line spectrum. The quantities in Heisenberg's formulation were the classical position and momentum, but now they were no longer sharply defined. Each quantity was represented by a collection of Fourier coefficients with two indices, corresponding to the initial and final states.
When Born read the paper, he recognized the formulation as one which could be transcribed and extended to the systematic language of matrices, which he had learned from his study under Jakob Rosanes at Breslau University. Born, with the help of his assistant and former student Pascual Jordan, began immediately to make the transcription and extension, and they submitted their results for publication; the paper was received for publication just 60 days after Heisenberg's paper.
A follow-on paper was submitted for publication before the end of the year by all three authors. (A brief review of Born's role in the development of the matrix mechanics formulation of quantum mechanics along with a discussion of the key formula involving the non-commutivity of the probability amplitudes can be found in an article by Jeremy Bernstein. A detailed historical and technical account can be found in Mehra and Rechenberg's book )The Historical Development of Quantum Theory. Volume 3. The Formulation of Matrix Mechanics and Its Modifications 1925–1926.
Up until this time, matrices were seldom used by physicists; they were considered to belong to the realm of pure mathematics. Gustav Mie had used them in a paper on electrodynamics in 1912 and Born had used them in his work on the lattices theory of crystals in 1921. While matrices were used in these cases, the algebra of matrices with their multiplication did not enter the picture as they did in the matrix formulation of quantum mechanics.
Born, however, had learned matrix algebra from Rosanes, as already noted, but Born had also learned Hilbert's theory of integral equations and quadratic forms for an infinite number of variables as was apparent from a citation by Born of Hilbert's work Grundzüge einer allgemeinen Theorie der Linearen Integralgleichungen published in 1912.
Jordan, too, was well equipped for the task. For a number of years, he had been an assistant to Richard Courant at Göttingen in the preparation of Courant and David Hilbert's book Methoden der mathematischen Physik I, which was published in 1924. This book, fortuitously, contained a great many of the mathematical tools necessary for the continued development of quantum mechanics.
In 1926, John von Neumann became assistant to David Hilbert, and he would coin the term Hilbert space to describe the algebra and analysis which were used in the development of quantum mechanics.
A linchpin contribution to this formulation was achieved in Dirac's reinterpretation/synthesis paper of 1925,  which invented the language and framework usually employed today, in full display of the noncommutative structure of the entire construction.
Before matrix mechanics, the old quantum theory described the motion of a particle by a classical orbit, with well defined position and momentum X(t), P(t), with the restriction that the time integral over one period T of the momentum times the velocity must be a positive integer multiple of Planck's constant
When a classical particle is weakly coupled to a radiation field, so that the radiative damping can be neglected, it will emit . The frequencies that make up the outgoing wave are then integer multiples of the orbital frequency, and this is a reflection of the fact that X(t) is periodic, so that its Fourier representation has frequencies 2πn/T only.
A quantum mechanical particle, on the other hand, can not emit radiation continuously, it can only emit photons. Assuming that the quantum particle started in orbit number n, emitted a photon, then ended up in orbit number m, the energy of the photon is En−Em, which means that its frequency is (En − Em)/h.
Since the frequencies that the particle emits are the same as the frequencies in the Fourier description of its motion, this suggests that something in the time-dependent description of the particle is oscillating with frequency (En−Em)/h. Heisenberg called this quantity Xnm, and demanded that it should reduce to the classical Fourier coefficients in the classical limit. For large values of n, m but with n − m relatively small, Xnm is the (n−m)th Fourier coefficient of the classical motion at orbit n. Since Xnm has opposite frequency to Xmn, the condition that X is real becomes
By definition, Xnm only has the frequency (En−Em)/h, so its time evolution is simple:
Given two arrays Xnm and Pnm describing two physical quantities, Heisenberg could form a new array of the same type by combining the terms XnkPkm, which also oscillate with the right frequency. Since the Fourier coefficients of the product of two quantities is the convolution of the Fourier coefficients of each one separately, the correspondence with Fourier series allowed Heisenberg to deduce the rule by which the arrays should be multiplied,
Born pointed out that this is the law of matrix multiplication, so that the position, the momentum, the energy, all the observable quantities in the theory, are interpreted as matrices. Under this multiplication rule, the product depends on the order: XP is different from PX.
The X matrix is a complete description of the motion of a quantum mechanical particle. Because the frequencies in the quantum motion are not multiples of a common frequency, the matrix elements . Nevertheless, as matrices, X(t) and P(t) satisfy the classical equations of motion; also see Ehrenfest's theorem, below.cannot be interpreted as the Fourier coefficients of a sharp classical trajectory
When it was introduced by Werner Heisenberg, Max Born and Pascual Jordan in 1925, matrix mechanics was not immediately accepted and was a source of controversy, at first. Schrödinger's later introduction of wave mechanics was greatly favored.
Part of the reason was that Heisenberg's formulation was in an odd mathematical language, for the time, while Schrödinger's formulation was based on familiar wave equations. But there was also a deeper sociological reason. Quantum mechanics had been developing by two paths, one led by Einstein, who emphasized the wave–particle duality he proposed for photons, and the other led by Bohr, that emphasized the discrete energy states and quantum jumps that Bohr discovered. De Broglie had reproduced the discrete energy states within Einstein's framework—the quantum condition is the standing wave condition, and this gave hope to those in the Einstein school that all the discrete aspects of quantum mechanics would be subsumed into a continuous wave mechanics.
Matrix mechanics, on the other hand, came from the Bohr school, which was concerned with discrete energy states and quantum jumps. Bohr's followers did not appreciate physical models that pictured electrons as waves, or as anything at all. They preferred to focus on the quantities that were directly connected to experiments.
In atomic physics, spectroscopy gave observational data on atomic transitions arising from the interactions of atoms with light quanta. The Bohr school required that only those quantities that were in principle measurable by spectroscopy should appear in the theory. These quantities include the energy levels and their intensities but they do not include the exact location of a particle in its Bohr orbit. It is very hard to imagine an experiment that could determine whether an electron in the ground state of a hydrogen atom is to the right or to the left of the nucleus. It was a deep conviction that such questions did not have an answer.
The matrix formulation was built on the premise that all physical observables are represented by matrices, whose elements are indexed by two different energy levels. The set of eigenvalues of the matrix were eventually understood to be the set of all possible values that the observable can have. Since Heisenberg's matrices are Hermitian, the eigenvalues are real.
If an observable is measured and the result is a certain eigenvalue, the corresponding eigenvector is the state of the system immediately after the measurement. The act of measurement in matrix mechanics 'collapses' the state of the system. If one measures two observables simultaneously, the state of the system collapses to a common eigenvector of the two observables. Since most matrices don't have any eigenvectors in common, most observables can never be measured precisely at the same time. This is the uncertainty principle.
If two matrices share their eigenvectors, they can be simultaneously diagonalized. In the basis where they are both diagonal, it is clear that their product does not depend on their order because multiplication of diagonal matrices is just multiplication of numbers. The uncertainty principle, by contrast, is an expression of the fact that often two matrices A and B do not always commute, i.e., that AB − BA does not necessarily equal 0. The fundamental commutation relation of matrix mechanics,there are no states that simultaneously have a definite position and momentum
This principle of uncertainty holds for many other pairs of observables as well. For example, the energy does not commute with the position either, so it is impossible to precisely determine the position and energy of an electron in an atom.
In 1928, Albert Einstein nominated Heisenberg, Born, and Jordan for the Nobel Prize in Physics. The announcement of the Nobel Prize in Physics for 1932 was delayed until November 1933. It was at that time that it was announced Heisenberg had won the Prize for 1932 "for the creation of quantum mechanics, the application of which has, inter alia, led to the discovery of the allotropic forms of hydrogen" and Erwin Schrödinger and Paul Adrien Maurice Dirac shared the 1933 Prize "for the discovery of new productive forms of atomic theory".
It might well be asked why Born was not awarded the Prize in 1932, along with Heisenberg, and Bernstein proffers speculations on this matter. One of them relates to Jordan joining the Nazi Party on May 1, 1933, and becoming a stormtrooper. Jordan's Party affiliations and Jordan's links to Born may well have affected Born's chance at the Prize at that time. Bernstein further notes that when Born finally won the Prize in 1954, Jordan was still alive, while the Prize was awarded for the statistical interpretation of quantum mechanics, attributable to Born alone.
Heisenberg's reactions to Born for Heisenberg receiving the Prize for 1932 and for Born receiving the Prize in 1954 are also instructive in evaluating whether Born should have shared the Prize with Heisenberg. On November 25, 1933, Born received a letter from Heisenberg in which he said he had been delayed in writing due to a "bad conscience" that he alone had received the Prize "for work done in Göttingen in collaboration – you, Jordan and I." Heisenberg went on to say that Born and Jordan's contribution to quantum mechanics cannot be changed by "a wrong decision from the outside."
In 1954, Heisenberg wrote an article honoring Max Planck for his insight in 1900. In the article, Heisenberg credited Born and Jordan for the final mathematical formulation of matrix mechanics and Heisenberg went on to stress how great their contributions were to quantum mechanics, which were not "adequately acknowledged in the public eye."
Once Heisenberg introduced the matrices for X and P, he could find their matrix elements in special cases by guesswork, guided by the correspondence principle. Since the matrix elements are the quantum mechanical analogs of Fourier coefficients of the classical orbits, the simplest case is the harmonic oscillator, where the classical position and momentum, X(t) and P(t), are sinusoidal.
In units where the mass and frequency of the oscillator are equal to one (see nondimensionalization), the energy of the oscillator is
The level sets of H are the clockwise orbits, and they are nested circles in phase space. The classical orbit with energy E is
The old quantum condition dictates that the integral of P dX over an orbit, which is the area of the circle in phase space, must be an integer multiple of Planck's constant. The area of the circle of radius √2E is 2πE. So
The Fourier components of X(t) and P(t) are simple, and more so if they are combined into the quantities
Since A(t) has a classical Fourier series with only the lowest frequency, and the matrix element Amn is the (m − n)-th Fourier coefficient of the classical orbit, the matrix for A is nonzero only on the line just above the diagonal, where it is equal to √2En. The matrix for A† is likewise only nonzero on the line below the diagonal, with the same elements. Thus, from A and A†, reconstruction yields
Finding X(t) and P(t) is direct, since they are quantum Fourier coefficients so they evolve simply with time,
The matrix product of X and P is not hermitian, but has a real and imaginary part. The real part is one half the symmetric expression XP + PX, while the imaginary part is proportional to the commutator
The harmonic oscillator is an important case. Finding the matrices is easier than determining the general conditions from these special forms. For this reason, Heisenberg investigated the anharmonic oscillator, with Hamiltonian
In this case, the X and P matrices are no longer simple off diagonal matrices, since the corresponding classical orbits are slightly squashed and displaced, so that they have Fourier coefficients at every classical frequency. To determine the matrix elements, Heisenberg required that the classical equations of motion be obeyed as matrix equations,
He noticed that if this could be done, then H, considered as a matrix function of X and P, will have zero time derivative.
Given that all the off diagonal elements have a nonzero frequency; H being constant implies that H is diagonal. It was clear to Heisenberg that in this system, the energy could be exactly conserved in an arbitrary quantum system, a very encouraging sign.
The process of emission and absorption of photons seemed to demand that the conservation of energy will hold at best on average. If a wave containing exactly one photon passes over some atoms, and one of them absorbs it, that atom needs to tell the others that they can't absorb the photon anymore. But if the atoms are far apart, any signal cannot reach the other atoms in time, and they might end up absorbing the same photon anyway and dissipating the energy to the environment. When the signal reached them, the other atoms would have to somehow recall that energy. This paradox led Bohr, Kramers and Slater to abandon exact conservation of energy. Heisenberg's formalism, when extended to include the electromagnetic field, was obviously going to sidestep this problem, a hint that the interpretation of the theory will involve wavefunction collapse.
Demanding that the classical equations of motion are preserved is not a strong enough condition to determine the matrix elements. Planck's constant does not appear in the classical equations, so that the matrices could be constructed for many different values of ħ and still satisfy the equations of motion, but with different energy levels.
So, in order to implement his program, Heisenberg needed to use the old quantum condition to fix the energy levels, then fill in the matrices with Fourier coefficients of the classical equations, then alter the matrix coefficients and the energy levels slightly to make sure the classical equations are satisfied. This is clearly not satisfactory. The old quantum conditions refer to the area enclosed by the sharp classical orbits, which do not exist in the new formalism.
The most important thing that Heisenberg discovered is how to translate the old quantum condition into a simple statement in matrix mechanics.
There are several problems with this integral, all stemming from the incompatibility of the matrix formalism with the old picture of orbits. Which period T should be used? Semiclassically, it should be either m or n, but the difference is order ħ, and an answer to order ħ is sought. The quantum condition tells us that Jmn is 2πn on the diagonal, so the fact that J is classically constant tells us that the off-diagonal elements are zero.
His crucial insight was to differentiate the quantum condition with respect to n. This idea only makes complete sense in the classical limit, where n is not an integer but the continuous action variable J, but Heisenberg performed analogous manipulations with matrices, where the intermediate expressions are sometimes discrete differences and sometimes derivatives.
In the following discussion, for the sake of clarity, the differentiation will be performed on the classical variables, and the transition to matrix mechanics will be done afterwards, guided by the correspondence principle.
In the classical setting, the derivative is the derivative with respect to J of the integral which defines J, so it is tautologically equal to 1.
The final expression is clarified by introducing the variable canonically conjugate to J, which is called the angle variable θ: The derivative with respect to time is a derivative with respect to θ, up to a factor of 2πT,
The Poisson Bracket, unlike the action integral, does have a simple translation to matrix mechanics−−it normally corresponds to the imaginary part of the product of two variables, the commutator.
To see this, examine the (antisymmetrized) product of two matrices A and B in the correspondence limit, where the matrix elements are slowly varying functions of the index, keeping in mind that the answer is zero classically.
In the correspondence limit, when indices m, n are large and nearby, while k,r are small, the rate of change of the matrix elements in the diagonal direction is the matrix element of the J derivative of the corresponding classical quantity. So its possible to shift any matrix element diagonally through the correspondence,
The semiclassical time derivative of a matrix element is obtained up to a factor of i by multiplying by the distance from the diagonal,
The imaginary part of the product of A and B can be evaluated by shifting the matrix elements around so as to reproduce the classical answer, which is zero.
The leading nonzero residual is then given entirely by the shifting. Since all the matrix elements are at indices which have a small distance from the large index position (m,m), it helps to introduce two temporary notations: A[r,k] = A(m+r)(m+k) for the matrices, and (dA/dJ)[r] for the r'th Fourier components of classical quantities,
Flipping the summation variable in the first sum from r to r' = k − r, the matrix element becomes,
The leading quantum part, neglecting the higher order product of derivatives in the residual expression, is then equal to
Heisenberg's original differentiation trick was eventually extended to a full semiclassical derivation of the quantum condition, in collaboration with Born and Jordan. Once they were able to establish that
The new quantization rule was assumed to be universally true, even though the derivation from the old quantum theory required semiclassical reasoning. (A full quantum treatment, however, for more elaborate arguments of the brackets, was appreciated in the 1940s to amount to extending Poisson brackets to Moyal brackets.)
To make the transition to standard quantum mechanics, the most important further addition was the quantum state vector, now written |ψ⟩, which is the vector that the matrices act on. Without the state vector, it is not clear which particular motion the Heisenberg matrices are describing, since they include all the motions somewhere.
The interpretation of the state vector, whose components are written ψm, was furnished by Born. This interpretation is statistical: the result of a measurement of the physical quantity corresponding to the matrix A is random, with an average value equal to
Once the state vector was introduced, matrix mechanics could be rotated to any basis, where the H matrix need no longer be diagonal. The Heisenberg equation of motion in its original form states that Amn evolves in time like a Fourier component,
All these forms of the equation of motion above say the same thing, that A(t) is equivalent to A(0), through a basis rotation by the unitary matrix eiHt, a systematic picture elucidated by Dirac in his bra–ket notation.
Conversely, by rotating the basis for the state vector at each time by eiHt, the time dependence in the matrices can be undone. The matrices are now time independent, but the state vector rotates,
The Heisenberg picture does not distinguish time from space, so it is better suited to relativistic theories than the Schrödinger equation. Moreover, the similarity to classical physics is more manifest: the Hamiltonian equations of motion for classical mechanics are recovered by replacing the commutator above by the Poisson bracket (see also below). By the Stone–von Neumann theorem, the Heisenberg picture and the Schrödinger picture must be unitarily equivalent, as detailed below.
Matrix mechanics rapidly developed into modern quantum mechanics, and gave interesting physical results on the spectra of atoms.
Jordan noted that the commutation relations ensure that P acts as a differential operator.
Assuming limits are defined sensibly, this extends to arbitrary functions−−but the extension need not be made explicit until a certain degree of mathematical rigor is required,
Since X is a Hermitian matrix, it should be diagonalizable, and it will be clear from the eventual form of P that every real number can be an eigenvalue. This makes some of the mathematics subtle, since there is a separate eigenvector for every point in space.
In the basis where X is diagonal, an arbitrary state can be written as a superposition of states with eigenvalues x,
Hence, there is always a basis for the eigenvalues of X where the action of P on any wavefunction is known:
Thus, the equation of motion for the state vector is but a celebrated differential equation,
Since D is a differential operator, in order for it to be sensibly defined, there must be eigenvalues of X which neighbors every given value. This suggests that the only possibility is that the space of all eigenvalues of X is all real numbers, and that P is iD, up to a phase rotation.
To make this rigorous requires a sensible discussion of the limiting space of functions, and in this space this is the Stone–von Neumann theorem: any operators X and P which obey the commutation relations can be made to act on a space of wavefunctions, with P a derivative operator. This implies that a Schrödinger picture is always available.
Matrix mechanics easily extends to many degrees of freedom in a natural way. Each degree of freedom has a separate X operator and a separate effective differential operator P, and the wavefunction is a function of all the possible eigenvalues of the independent commuting X variables.
In particular, this means that a system of N interacting particles in 3 dimensions is described by one vector whose components in a basis where all the X are diagonal is a mathematical function of 3N-dimensional space describing all their possible positions, effectively a much bigger collection of values than the mere collection of N three-dimensional wavefunctions in one physical space. Schrödinger came to the same conclusion independently, and eventually proved the equivalence of his own formalism to Heisenberg's.
Since the wavefunction is a property of the whole system, not of any one part, the description in quantum mechanics is not entirely local. The description of several quantum particles has them correlated, or entangled. This entanglement leads to strange correlations between distant particles which violate the classical Bell's inequality.
Even if the particles can only be in just two positions, the wavefunction for N particles requires 2N complex numbers, one for each total configuration of positions. This is exponentially many numbers in N, so simulating quantum mechanics on a computer requires exponential resources. Conversely, this suggests that it might be possible to find quantum systems of size N which physically compute the answers to problems which classically require 2N bits to solve. This is the aspiration behind quantum computing.
For the time-independent operators X and P, ∂A/∂t = 0 so the Heisenberg equation above reduces to:
So Newton's laws are exactly obeyed by the expected values of the operators in any given state. This is Ehrenfest's theorem, which is an obvious corollary of the Heisenberg equations of motion, but is less trivial in the Schrödinger picture, where Ehrenfest discovered it.
In classical mechanics, a canonical transformation of phase space coordinates is one which preserves the structure of the Poisson brackets. The new variables x',p' have the same Poisson brackets with each other as the original variables x,p. Time evolution is a canonical transformation, since the phase space at any time is just as good a choice of variables as the phase space at any other time.
Since the Hamiltonian can be an arbitrary function of x and p, there are such infinitesimal canonical transformations corresponding to every classical quantity G, where G serves as the Hamiltonian to generate a flow of points in phase space for an increment of time s,
For a general function A(x, p) on phase space, its infinitesimal change at every step ds under this map is
In quantum mechanics, the quantum analog G is now a Hermitian matrix, and the equations of motion are given by commutators,
The infinitesimal canonical motions can be formally integrated, just as the Heisenberg equation of motion were integrated,
The definition of a quantum canonical transformation is thus an arbitrary unitary change of basis on the space of all state vectors. U is an arbitrary unitary matrix, a complex rotation in phase space,
The interpretation of the matrices is that they act as generators of motions on the space of states.
For example, the motion generated by P can be found by solving the Heisenberg equation of motion using P as a Hamiltonian,
The X operator likewise generates translations in P. The Hamiltonian generates translations in time, the angular momentum generates rotations in physical space, and the operator X 2 + P 2 generates rotations in phase space.
When a transformation, like a rotation in physical space, commutes with the Hamiltonian, the transformation is called a symmetry (behind a degeneracy) of the Hamiltonian−−the Hamiltonian expressed in terms of rotated coordinates is the same as the original Hamiltonian. This means that the change in the Hamiltonian under the infinitesimal symmetry generator L vanishes,
It then follows that the change in the generator under time translation also vanishes,
The one-to-one association of infinitesimal symmetry generators and conservation laws was discovered by Emmy Noether for classical mechanics, where the commutators are Poisson brackets, but the quantum-mechanical reasoning is identical. In quantum mechanics, any unitary symmetry transformation yields a conservation law, since if the matrix U has the property that
The eigenvalues of unitary matrices are pure phases, so that the value of a unitary conserved quantity is a complex number of unit magnitude, not a real number. Another way of saying this is that a unitary matrix is the exponential of i times a Hermitian matrix, so that the additive conserved real quantity, the phase, is only well-defined up to an integer multiple of 2π. Only when the unitary symmetry matrix is part of a family that comes arbitrarily close to the identity are the conserved real quantities single-valued, and then the demand that they are conserved become a much more exacting constraint.
Symmetries which can be continuously connected to the identity are called continuous, and translations, rotations, and boosts are examples. Symmetries which cannot be continuously connected to the identity are discrete, and the operation of space-inversion, or parity, and charge conjugation are examples.
The interpretation of the matrices as generators of canonical transformations is due to Paul Dirac. The correspondence between symmetries and matrices was shown by Eugene Wigner to be complete, if antiunitary matrices which describe symmetries which include time-reversal are included.
It was physically clear to Heisenberg that the absolute squares of the matrix elements of X, which are the Fourier coefficients of the oscillation, would yield the rate of emission of electromagnetic radiation.
In the classical limit of large orbits, if a charge with position X(t) and charge q is oscillating next to an equal and opposite charge at position 0, the instantaneous dipole moment is q X(t), and the time variation of this moment translates directly into the space-time variation of the vector potential, which yields nested outgoing spherical waves.
For atoms, the wavelength of the emitted light is about 10,000 times the atomic radius, and the dipole moment is the only contribution to the radiative field, while all other details of the atomic charge distribution can be ignored.
Ignoring back-reaction, the power radiated in each outgoing mode is a sum of separate contributions from the square of each independent time Fourier mode of d,
Now, in Heisenberg's representation, the Fourier coefficients of the dipole moment are the matrix elements of X. This correspondence allowed Heisenberg to provide the rule for the transition intensities, the fraction of the time that, starting from an initial state i, a photon is emitted and the atom jumps to a final state j,
This then allowed the magnitude of the matrix elements to be interpreted statistically: .they give the intensity of the spectral lines, the probability for quantum jumps from the emission of dipole radiation
Since the transition rates are given by the matrix elements of X, wherever Xij is zero, the corresponding transition should be absent. These were called the selection rules, which were a puzzle until the advent of matrix mechanics.
An arbitrary state of the Hydrogen atom, ignoring spin, is labelled by |n;ℓ,m ⟩, where the value of ℓ is a measure of the total orbital angular momentum and m is its z-component, which defines the orbit orientation. The components of the angular momentum pseudovector are
The commutation relations of L with all three coordinate matrices X, Y, Z (or with any vector) are easy to find,
From this, the commutator of Lz and the coordinate matrices X, Y, Z can be read off,
This means that the quantities X + iY, X − iY have a simple commutation rule,
Just like the matrix elements of X + iP and X − iP for the harmonic oscillator Hamiltonian, this commutation law implies that these operators only have certain off diagonal matrix elements in states of definite m,
So, in a basis of |ℓ,m⟩ states where L2 and Lz have definite values, the matrix elements of any of the three components of the position are zero, except when m is the same or changes by one unit.
This places a constraint on the change in total angular momentum. Any state can be rotated so that its angular momentum is in the z-direction as much as possible, where m = ℓ. The matrix element of the position acting on |ℓ,m⟩ can only produce values of m which are bigger by one unit, so that if the coordinates are rotated so that the final state is |ℓ',ℓ' ⟩, the value of ℓ’ can be at most one bigger than the biggest value of ℓ that occurs in the initial state. So ℓ’ is at most ℓ + 1.
The matrix elements vanish for ℓ’ > ℓ + 1, and the reverse matrix element is determined by Hermiticity, so these vanish also when ℓ’ < ℓ - 1: Dipole transitions are forbidden with a change in angular momentum of more than one unit.
The Heisenberg equation of motion determines the matrix elements of P in the Heisenberg basis from the matrix elements of X.
This yields a relation for the sum of the spectroscopic intensities to and from any given state, although to be absolutely correct, contributions from the radiative capture probability for unbound scattering states must be included in the sum: